In the spring of 1811, 35-year-old col lege professor Amedeo Avogadro sat in his classroom scowling at two scientific papers laid out on his desk. Avogadro taught natural science classes at Vercelli Col lege in the Italian mountain town of Turin. Twenty-five students sat each day and listened to Professor Avogadro lecture, discuss, and quiz them on what ever aspects of science caught his fancy.
This day he read these two papers to his class, claimed that he saw an important mystery in them, and challenged his students to find it. In the two papers, the English chemist, Dalton, and the French chemist, Gay-Lussac, each described an experiment in which they combined hydrogen and oxygen atoms to create water. Both re ported that it took exactly two liters of gaseous hydrogen atoms to combine with exactly one liter of oxygen atoms to produce exactly two liters of gaseous water vapor.
Dalton claimed that this experiment proved that water is the combination of two atoms of hydrogen and one atom of oxygen. Gay-Lussac also claimed it proved that a liter of any gas had to contain exactly the same number of atoms as a liter of any other gas, no matter what gas it was.
These studies were heralded as major breakthroughs for chemical study. But from his first reading, Professor Avogadro was bothered by a nagging contradiction.
Both Dalton and Gay-Lus sacstarted with exactly two liters of hydrogen and one liter of oxygen. That's a total of three liters of gas. But they both ended with only two liters of water vapor gas. If every liter of every gas has to have exactly the same number of atoms, then how could all the atoms from three liters of gas fit into just two liters of water va por gas?
The Turin cathedral bell chimed midnight before the answer struck Avogadro's mind.
Dalton and Gay-Lus sac had used the wrong word. What if they had each substituted “a group of attached atoms” for atom?Avogadro created the word molecule (a Greek word meaning, “to move about freely in a gas”) for this “group of attached atoms.”
Then he scratched out equations on pa per until he found a way to account for all of the atoms and molecules in Dalton's and Gay-Lussac's experiments. If each molecule of hydrogen contained two atoms of hydrogen, and each molecule of oxygen contained two atoms of oxygen, then, if each molecule of wa ter vapor contained two atoms of hydrogen and one atom of oxygen, as both scientists reported, each liter of
hydrogen and each liter of oxygen would have exactly the same number of molecules as each of the two resulting liters of water va por (even though they contained a different number of atoms)!
And so it was that, without ever touching a test tube or chemical experiment of any kind, without even a background in chemistry, Amedeo Avogadro discovered the existence of molecules and created the basic gas law every liter of a gas contains the same number of molecules of gas.
